We consider the problem of factorizing a structured 3-way tensor into its constituent Canonical Polyadic (CP) factors. This decomposition, which can be viewed as a generalization of singular value decomposition (SVD) for tensors, reveals how the tensor dimensions (features) interact with each other. However, since the factors are a priori unknown, the corresponding optimization problems are inherently non-convex. The existing guaranteed algorithms which handle this non-convexity incur an irreducible error (bias), and only apply to cases where all factors have the same structure. To this end, we develop a provable algorithm for online structured tensor factorization, wherein one of the factors obeys some incoherence conditions, and the others are sparse. Specifically we show that, under some relatively mild conditions on initialization, rank, and sparsity, our algorithm recovers the factors exactly (up to scaling and permutation) at a linear rate. Complementary to our theoretical results, our synthetic and real-world data evaluations showcase superior performance compared to related techniques.