This study investigates why and how inconsistency in the generation of Large Language Models (LLMs) might induce or exacerbate societal injustice. For instance, LLMs frequently exhibit contrasting gender stereotypes regarding the same career depending on varied contexts, highlighting the arguably harmful unpredictability of LLMs' behavioral patterns. To augment the existing discrimination assessment with the capability to account for variation in LLM generation, we formulate the Prejudice-Volatility Framework (PVF) that precisely defines behavioral metrics for assessing LLMs, which delineate the probability distribution of LLMs' stereotypes from the perspective of token prediction probability. Specifically, we employ a data-mining approach to approximate the possible applied contexts of LLMs and devise statistical metrics to evaluate the corresponding contextualized societal discrimination risk. Further, we mathematically dissect the aggregated discrimination risk of LLMs into prejudice risk, originating from their system bias, and volatility risk, stemming from their generation inconsistency. While initially intended for assessing discrimination in LLMs, our proposed PVF facilitates the comprehensive and flexible measurement of any inductive biases, including knowledge alongside prejudice, across various modality models.We apply PVF to the 12 most commonly adopted LLMs and compare their risk levels. Our findings reveal that: i) prejudice risk is the primary cause of discrimination risk in LLMs, indicating that inherent biases in these models lead to stereotypical outputs; ii) most LLMs exhibit significant pro-male stereotypes across nearly all careers; iii) alignment with Reinforcement Learning from Human Feedback lowers discrimination by reducing prejudice, but increases volatility; iv) discrimination risk in LLMs correlates with key socio-economic factors like profession salaries.